Lanthanide-based bis-(3,5-dicarboxy-phenyl)terephthalamide metal–organic frameworks: slow relaxation of magnetization and detection of trace Fe²⁺ and Fe³⁺

Qingfang Lin,Wen Xie,Zhihui Zong,Zicheng Liu,Yuqing Sun,Lili Liang

New Journal of Chemistry（2021）

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摘要

{[Dy2(BDPT)1.5(DMF)4]·H2O}n (1) and [Sm2(BDPT)1.5(DMF)4]n (2) were prepared with highly sensitive fluorescent detection of trace Fe2+ and Fe3+. 1 exhibits weak antiferromagnetic interactions with signature of SMM behavior.

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Lanthanide-based bis-(3,5-dicarboxy-phenyl)terephthalamide metal–organic frameworks: slow relaxation of magnetization and detection of trace Fe2+ and Fe3+

Lanthanide-based bis-(3,5-dicarboxy-phenyl)terephthalamide metal–organic frameworks: slow relaxation of magnetization and detection of trace Fe²⁺ and Fe³⁺