Isotopic and geochemical constraints on the protolith, redox state and paleo-tectonic setting of the Malagarasi Supergroup of north-western Tanzania

We report detrital zircon U-Pb ages, radiogenic Sm-Nd isotopic compositions, major and trace element compositions of the intra-plate extensional rhomb-shaped Neoproterozoic Malagarasi Supergroup of north-western Tanzania in order to elucidate the paleo-tectonic setting, source rocks chemistry and paleo-oxygenation in the basin. Assuming that provenance trace element proxy ratios, including the rare earth elements (REE) contents, behave as closed systems during sedimentation and diagenesis, we suggest that the detritus for the Malagarasi Supergroup originated from more felsic rocks than those for upper crustal composites (i.e. Post-Archean Australian Shale; PAAS, Proterozoic Shale; PS). This observation is also supported by enriched chondritenormalized light REE (La/Sm-CN = 2.36-7.84; mean = 3.85), overall negative Eu anomalies (Eu/Eu* = 0.56-0.93; mean = 0.69) and flat heavy REE patterns (Gd/Yb-CN = 1.01-2.04; mean = 1.47). Paleo-weathering proxies using the Chemical Index of Alteration (CIA similar to 59-78%) protocol indicate an overall moderate weathering intensity in the basin. V/Cr ratios (mean = 1.18; range = 0.48-1.69) coupled with intra-sample Ce anomalies reveal an overall oxidizing state during deposition. Mantle extraction ages (T-DM = 1594-2394 Ma) suggest a diverse mixing of protolith terranes including Archean (Tanzania craton), Eburnian (Ubendian Belt) and possibly the nearby Mesoproterozoic Kibaran Belt. Radiogenic laser ablation detrital zircon U-Pb ages of between 1826 and 2656 Ma may preclude contribution from the Kibaran. Given that Nd systematics in sedimentary rocks provide mixing ages of different hinterland source rocks (1594-2394 Ma; in our study), we suggest relatively juvenile sources such as the local post-orogenic effusive bodies farther south of the basin in the realm of Rodinia Supercontinent. Thus, a northerly flow direction of the of the proto/paleo river system in the region is inferred.