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Performance study and comparison between catalytic static mixer and packed bed in heterogeneous hydrogenation of vinyl acetate

JOURNAL OF FLOW CHEMISTRY(2021)

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摘要
Catalytic Static Mixers (CSMs) used in a continuous flow reactor for heterogeneous catalysis have been compared with packed bed reactor technology for the hydrogenation of vinyl acetate to ethyl acetate over 5 wt-% Pd/Al 2 O 3 catalyst. The CSM reactor showed lower pressure drop, better heat transfer, and higher conversion and turnover frequency compared to a traditional packed bed reactor. A reaction performance study with varying CSM length has been performed and shows that the hydrogenation reactions are limited by the chemical reaction kinetics and not by the mass transfer.
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关键词
Heterogeneous catalysis,Flow chemistry,Hydrogenation,Palladium,Pressure drop,Heat transfer,Mass transfer
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