Synthesis and Characterisation of Boranediyl- and Diboranediyl-Bridged Diplatinum A-frame Complexes.

Carina Brunecker,Merle Arrowsmith,Jonas H. Mussig,Julian Bohnke,Andreas Stoy,Merlin Hess,Alexander Hofmann,Carsten Lenczyk,Crispin Lichtenberg,Jacqueline Ramler,Anna Rempel,Holger Braunschweig

Dalton transactions（2021）

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摘要

(Di)boranediyl-bridged diplatinum A-frame complexes were synthesised by the twofold oxidative addition of dihalo(di)boranes to a bis(diphosphine)-bridged diplatinum(0) precursor and were characterised by NMR spectroscopy and X-ray crystallography.

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