Construction of Bicyclic 1,2,3-Triazine N-Oxides from Aminocyanides.
Organic letters(2020)
摘要
Using a facile and cost-effective method, nine bicyclic 1,2,3-triazine 2-oxides were synthesized from o-aminocyanide substrates through an unusual nitration cyclization. The reaction mechanism was studied experimentally and theoretically. Moreover, nine 1,2,3-triazine 3-oxides were also obtained in good yields.
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