A novel stainless steel fiber felt/Pd nanocatalysts electrode for efficient ORR in air-cathode microbial fuel cells
Electrochimica Acta(2019)
摘要
A 3D macroporous stainless steel fiber felt (SSFF) is used as base material and a simple water bath method is adopted to directly load Pd nanocatalysts on SSFF to fabricate the air cathode of microbial fuel cells (MFCs). The optimum Pd loading is explored on the basis of the optimized PVP additive amount and reaction temperature. To attain a high ORR activity, a conductive carbon black filling layer is added into the 3D pores of Pd-SSFF. A series of physical and electrochemical tests are conducted to characterize the morphology, chemical composition and oxygen reduction activity and then the obtained cathodes are installed in MFCs for electricity production verification. The results show that the Pd-SSFF cathode at a Pd loading of 0.5 mg cm−2 (Pd-SSFF-0.5) achieves high output voltage and power density (492.65 mV, 390.79 mW m−2) which are comparable to the conventional Pt/C electrode (504.80 mV, 405.47 mW m−2). Furthermore, with Pd-SSFF-0.5 cathode the high-voltage platform duration of MFC in one operation cycle is 2.79 times of that of Pt/C electrode. Excellent mechanical properties (high pressure and corrosion tolerance), high electric energy output and simple fabrication prove it is an efficient strategy to improve the overall performance of MFCs using the obtained cathodes.
更多查看译文
关键词
Microbial fuel cells,Air cathode,Stainless steel fiber felt,Oxygen reduction activity,Three-phase interface
AI 理解论文
溯源树
样例
![](https://originalfileserver.aminer.cn/sys/aminer/pubs/mrt_preview.jpeg)
生成溯源树,研究论文发展脉络
Chat Paper
正在生成论文摘要