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Trifluoromethylated Morpholines Condensed with Oxetane: Synthesis and Transformations

Alexander Yu. Rulev,Alexey R. Romanov,Evgeniy V. Kondrashov,Igor A. Ushakov,Vasiliy M. Muzalevskiy,Valentine G. Nenajdenko

Journal of fluorine chemistry（2019）

Cited 2|Views39
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Abstract
The treatment of fluorinated a-bromoenones with amino diols leads mainly to bicyclic compounds bearing condensed morpholine and oxetane rings. These derivatives undergo spontaneous isomerization into bisoxazines when standing in a chloroform solution at room temperature.
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Key words
Fluorinated azaheterocycles,Condensed bicycles,Morpholine,Oxetane,Trifluoromethyl group
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