Synthesis of zeolite SSZ-13 from coal gangue via ultrasonic pretreatment combined with hydrothermal growth method.

SSZ-13 zeolite has been widely used in catalysis and adsorption because of good hydrothermal stability and pore structure. However, long crystallization time is the main challenge limiting its industry application. As increased emissions and ineffective treatment, coal gangue not only occupies land, but also pollutes the waterbody and farmland. Using coal gangue as raw material to synthetize zeolite has been considered as an environmentally friendly and effective alternative to solve the issues of accumulation and pollution, which also improves the added value of coal gangue. The ultrasonic assistance has been proven to be one of the potential pretreatment methods to promote the dissolution of crystalline silicon aluminum and reduce the crystallization time of molecular sieve. In this work, SSZ-13 was synthesized by coal gangue via ultrasonic pretreatment combined with hydrothermal growth method. The ultrasonic frequency and power were 20 kHz and 120 W, respectively. The synthesized samples were characterized by XRD, SEM, EDS, BET. The results showed that the crystallization time was shorten to 18 h, which was about 12 h lower than the same conditions of conventional chemicals synthesis. Furthermore, the specific surface area of the synthesized sample was more than 620 m2/g, which also indicated over 95% NOx conversion across a broad range from 180 to 400 °C and over 94% NOx conversion at 200-400 °C after hydrothermal treatment 6 h. This study provides a reference for the environmentally friendly utilization of coal gangue and the low-cost rapid synthesis and application of SSZ-13.