Synthesis of Cyclotriveratrylene-Sucrose-Based Capsules

Łukasz Szyszka,Piotr Cmoch,Aleksandra Butkiewicz,Mykhaylo A Potopnyk,Sławomir Jarosz

Organic Letters（2019）

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摘要

Cyclotriveratrylene (CTV) is a C3-symmetrical macrocycle, which can be used as a chiral building block in the construction of supramolecular containers. Coupling of the CTV unit with a sucrose molecule gave enantiopure water-soluble (after deprotection) containers. The absolute configuration of the synthesized capsules was determined by NMR and ECD spectroscopies and DFT calculations.

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关键词

capsules,cyclotriveratrylene-sucrose-based

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