Non-Hermitian bulk–boundary correspondence in quantum dynamics

Bulk–boundary correspondence, a guiding principle in topological matter, relates robust edge states to bulk topological invariants. Its validity, however, has so far been established only in closed systems. Recent theoretical studies indicate that this principle requires fundamental revisions for a wide range of open systems with effective non-Hermitian Hamiltonians. Therein, the intriguing localization of nominal bulk states at boundaries, known as the non-Hermitian skin effect, suggests a non-Bloch band theory in which non-Bloch topological invariants are defined in generalized Brillouin zones, leading to a general bulk–boundary correspondence beyond the conventional framework. Here, we experimentally observe this fundamental non-Hermitian bulk–boundary correspondence in discrete-time non-unitary quantum-walk dynamics of single photons. We demonstrate pronounced photon localizations near boundaries even in the absence of topological edge states, thus confirming the non-Hermitian skin effect. Facilitated by our experimental scheme of edge-state reconstruction, we directly measure topological edge states, which are in excellent agreement with the non-Bloch topological invariants. Our work unequivocally establishes the non-Hermitian bulk–boundary correspondence as a general principle underlying non-Hermitian topological systems and paves the way for a complete understanding of topological matter in open systems.