Spin-torsion dominated hyperfine splittings in the first excited torsional state (vt = 1) of methanol

Li-Hong Xu,J.T. Hougen,G.Yu. Golubiatnikov,S.P. Belov,A.V. Lapinov,E.A. Alekseev,I. Krapivin,L. Margulès,R.A. Motiyenko,S. Bailleux

Journal of Molecular Spectroscopy（2019）

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摘要

•Spin-torsion dominated hyperfine splittings in vt = 1 torsional state of methanol.•Proton-spin magnetic hyperfine interactions in E torsional states of methanol.•Least-squares fit to effective spin-rotation, spin-torsion, & spin–spin Hamiltonian.•Lamb-dip sub-mm-wave measurements for methanol from three laboratories.

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关键词

Effective Hamiltonian,First excited torsional E state,Least-squares fit,Magnetic hyperfine structure,Methanol,Spin-rotation interaction,Spin-torsion interaction

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Spin-torsion dominated hyperfine splittings in the first excited torsional state (vt = 1) of methanol

Spin-torsion dominated hyperfine splittings in the first excited torsional state (vt = 1) of methanol