Modeling of the bivariate molecular weight distribution-copolymer composition distribution in RAFT copolymerization using probability generating functions

Cecilia Fortunatti,Claudia Sarmoria,Adriana Brandolin,Mariano Asteasuain

Computational Materials Science（2017）

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摘要

•The RAFT copolymerization has been successfully modeled in detail using pgfs.•The model is capable of predicting the complete bivariate MWD-CCD.•Detailed information on the structure and process fundamentals may be obtained.•The model only requires the resources of a typical desktop PC.

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关键词

Modeling,Molecular weight distribution (MWD),Reversible addition fragmentation chain transfer (RAFT),Probability generating function (pgf),Copolymerization

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