Construction of a Mixed-Valence Mn16 Cluster with Four Tetrahedrons
Inorganic chemistry communications/Inorganic chemistry communications (Online)（2016）
Abstract
The synthesis, crystal structure, and magnetochemical properties of a mixed-valence Mn16 cluster are reported. The compound contains a Mn16(μ2-O)2(μ3-O)2(μ4-O)6 core, which is constructed from four tetrahedrons. Magnetic susceptibility measurements indicate the presence of dominant antiferromagnetic exchange interaction within the compound.
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Key words
Benzimidazole alkoxide ligand,Polynuclear manganese cluster,Crystal structure,Magnetic properties
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