Copper(I) oxalate complexes: Synthesis, structures and surprises

A. Timothy Royappa,Andrew D. Royappa,Raphael F. Moral,Arnold L. Rheingold,Robert J. Papoular, Deke M. Blum, Tien Q. Duong,Jacob R. Stepherson,Oliver D. Vu,Banghao Chen,Matthew R. Suchomel,James A. Golen,Gilles André,Nikolaos Kourkoumelis, Andrew D. Mercer, Allegra M. Pekarek, Dylan C. Kelly

Polyhedron（2016）

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摘要

A series of copper(I) oxalate complexes was synthesized by the simple reaction of Cu2O with oxalic acid in ethanol, and structurally characterized by X-ray diffraction, shedding light on their general structure and the mechanism of their disproportionation.

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关键词

Copper(I) oxide,Oxalate complexes,Coordination compounds,Chemical vapor deposition,Oxalic acid

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