A water soluble electro-catalyst for generating hydrogen based on a cobalt(III) complex supported by 1,10-phenanthroline
Chemical Physics Letters（2016）
Abstract
•Reaction of 1,10-phenanthroline (phen), Co(NO3)2·6H2O and tetracyanoethylene affords a complex, [(phen)3Co(CN)2]·NO3 1.•1 can electrocatalyze hydrogen evolution both from acetic acid and aqueous buffer.•This provides a method for water reduction catalysis using coordinatively saturated complexes in purely aqueous media.
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Key words
Coordinatively saturated cobalt(III) complex,Molecular catalyst,Proton or water reduction,Hydrogen generation
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