Structural and reactivity properties of perfluoroalkylphosphine complexes of platinum(0)

Polyhedron(2016)

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摘要
The first examples of structurally-characterized 2- and 3-coordinate Pt(0) complexes with π-acceptor perfluoroalkylphosphine ligands (PFAP’s) is reported. Addition of ethylene to (dfebp)2Pt (dfebp=(C2F5)2PtBu) results in facile and reversible equilibria with the ethylene adducts (dfebp)2Pt(C2H4) and (dfebp)Pt(C2H4)2.
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关键词
Phosphine complex,Pt(0),π-Acceptor phosphine coordination,2-Coordinate,3-Coordinate
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