Mathematical modelling of phase equilibria for supercritical CO 2 and polyethylene glycol of various molecular weights

The Journal of Supercritical Fluids（2014）

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摘要

•Modelling phase equilibria of PEG of various molecular weights and CO2.•Sanchez–Lacombe EOS and the Statistical Associating Fluid Theory were applied.•Binary interaction parameters optimized for the best fit with experimental data.•Assessing the effect of PEG molecular weight on binary interaction parameters.

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关键词

Sanchez–Lacombe equation of state,Statistical Associating Fluid Theory,Polyethylene glycol,Supercritical CO2,Solubility

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