Palladium-Catalyzed Carbon Isotope Exchange On Aliphatic And Benzoic Acid Chlorides
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY(2018)
摘要
An operationally simple protocol for a palladium-catalyzed (CO)-C-13 and (CO)-C-14 exchange with activated aliphatic and benzoic carbonyls is presented. Several C-13 and C-14 building blocks, natural product derivatives, and pharmaceuticals have been prepared to showcase the method for late-stage carbon isotope incorporation and its functional group compatibility.
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关键词
benzoic acid chlorides,carbon,palladium-catalyzed
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