Phosphoranide production and decomposition in the gas phase
International Journal of Mass Spectrometry(2014)
Abstract
•The mechanism for the production of phosphoranides is revealed.•Decomposition mechanism of phosphoranides was also thoroughly studied by DFT.•Thermodynamic and entropy effects for phosphoranide ion formation were studied.•Excellent agreement between DFT calculated and experimentally determined geometry parameters of phosphoranides are obtained.
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Key words
FT-ICR-MS,Reaction mechanism,Rearrangement,Energy barrier
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