Unusual transformations of the chrysanthemic nitrile skeleton by sodium hydride in n,n-dimethylformamide
TETRAHEDRON(1984)
摘要
It is shown that the title transformations occurred through basecatalyzed opening of the cyclopropane ring into the dienic nitrile 4 which then reacted with the in situ formed formaldehyde to yield the bicyclic compound 5 .
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关键词
chrysanthemic nitrile skeleton,sodium hydride,n-dimethylformamide
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