1H NMR studies of paramagnetic ferricytochrome c-551 from Pseudomonas aeruginosa at high pH: The role of histidine 16 in the spin transition
Polyhedron(2005)
Abstract
The electronic structure of ferricytochrome c-551 from Pseudomonas aeruginosa at high pH has been investigated using paramagnetic NMR techniques. The results indicate the existence of a spin transition associated to the deprotonation of histidine-16 axially bound to iron(III), which would trigger the decoordination of the second axial ligand, methionine-61.
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Key words
NMR,1D,2D,NOE,NOESY,EXSY,cyt c,PAGE,Pae
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