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The Use of Simple Sugars for the Synthesis of Chiral Monophilic Liquid Crystals

V VILL, F BACHMANN,J THIEM,IF PELYVAS, P PUDLO

Molecular crystals and liquid crystals science technology Section A, Molecular crystals and liquid crystals/Molecular crystals and liquid crystals science and technology Section A, Molecular crystals and liquid crystals（1992）

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Abstract
By Ferrier glycosylation of glycals and subsequent hydrogenation 2,3-dideoxyglycosides were obtained. Starting with glucose, xylose or rhamnose this reaction sequence led to thermotropic non-amphiphilic chiral liquid crystals. The synthesized compounds show cholesteric and smectic as well as blue and other cubic phases. The liquid crystalline properties were influenced by the anomeric effect. Key Words: deoxy sugarsFerrier reactionchiral liquid crystalscubic phaseoxygen heterocycles
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DEOXY SUGARS,FERRIER REACTION,CHIRAL LIQUID CRYSTALS,CUBIC PHASE,OXYGEN HETEROCYCLES
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