Anodic Behaviour of Lead Sulphide in Hydrochloric Acid
Journal of applied electrochemistry(1982)
摘要
The anodic dissolution of lead sulphide is studied at various chloride concentrations and at different pH values. At 25° C it is found that in hydrochloric acid the dissolution rate reaches a maximum around 3.0 mol dm−3. It has also been observed that at concentrations between 0.7 and 1.2 mol dm−3, a crystalline sulphur deposit formed during the dissolution process leads to an independent peak on theI-E curve whereas at higher concentrations it merges with the PbCl2 peak formation. pH has no significant effect on the dissolution rate. The results of a systematic study on the kinetics of the dissolution process as a function of concentration, temperature and pH are discussed.
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关键词
Sulphur,Chloride,Physical Chemistry,Sulphide,Hydrochloric Acid
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