On the reaction mechanism of MoS42− with nitric oxide
Inorganic Chemistry Communications(2010)
摘要
MoS42− (TTM) reacts in deaerated neutral phosphate buffered aqueous solutions with NO. Three consecutive reactions are observed. The two first ones obey pseudo first order rate laws with observed rates proportional to [NO]. The third reaction obeys a first order rate law. Nitrite is one of the final products.
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关键词
Tetrathiomolybdate,NO,Drug,Nitrosation,Radical mechanism
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