An unusual pathway of the oxidation of diethyl ether by bismuth(v) derivatives
Russian Chemical Bulletin（1995）
Abstract
Di(tert-butylperoxy)triphenylbismuth and the triphenylbismuth-tert-butyl hydroperoxide system transform diethyl ether into ethoxyacetic aldehyde. The latter undergoes further conversions under these reaction conditions to give the corresponding hydroxyperoxide, ethoxyacetic acid, and bismuth(III) acylates.
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Key words
diethyl ether, ethoxyacetic aldehyde, triphenylbismuth, tert-butyl hydroperoxide, oxidation
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