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A trinuclear heterobimetallic Ru(II)/Pt(II) complex as a chemodosimeter selective for sulfhydryl-containing amino acids and peptides.

Cheuk-Fai Chow,Brenda K W Chiu,Michael H W Lam,Wai-Yeung Wong

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY（2003）

Cited 138|Views5
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Abstract
A trinuclear heterobimetallic Ru(II)/Pt(II) complex, cis-{Ru(phen)2[CN-Pt(DMSO)Cl2]2} (phen = 1,10-phenanthroline), is able to function as a "switch-on" luminescent chemodosimeter for sulfhydryl-containing amino acids and peptides via specific binding of the amino acids/peptides with the Pt(II) centers and the subsequent cleavage of the Ru(II)-Pt(II) cyano-bridge.
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amino acid
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