Mass-Spectrometric and Ir Spectroscopic Study of the Perfluorobenzyl Radical

é. G. Baskir,V. A. Korolev,A. K. Mal'tsev, K. Uisasi,I. Tamash,O. M. Nefedov

Bulletin of the Academy of Sciences of the USSR, Division of Chemical Sciences（1989）

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摘要

Perfluorobenzyl radical generated by vacuum pyrolysis of perfluorobenzyl iodide was identified for the first time by mass spectrometry and matrix IR spectroscopy. The ionization potential of this radical was found to be 7.72 eV, and its IR spectrum in an argon matrix was recorded at 12 K.

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关键词

Mass Spectrometry,Benzene,Argon,Pyrolysis,Iodide

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