Highly Acidic N-Triflylphosphoramides as Chiral Brønsted Acid Catalysts: The Effect of Weak Hydrogen Bonds and Multiple Acceptors on Complex Structures and Aggregation

Markus Hecht,Philipp Dullinger, Wagner Silva,Dominik Horinek,Ruth Maria Gschwind

Chemical Science（2024）

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摘要

N-Triflylphosphoramides (NTPAs) represent an important catalyst class in asymmetric catalysis due to their multiple hydrogen bond acceptor sites and acidity, which is increased by several orders of magnitude compared to...

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