NHC/B(OH)3-mediated C3-selective acylation of unprotected monosaccharides: mechanistic insights and toward simpler/greener solutions

Jiamiao Jin, Jiangtao Guo, Feng Xu,Ya Lv,Guanjie Wang,Jia Song,Wen-Xin Lv,Tingting Li, Yonggui Robin Chi

Green Chemistry(2024)

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摘要
A simple and greener protocol for the regio-selective acylation of unprotected monosaccharides is achieved using boric acid as a promoter and N-heterocyclic carbene as an organic catalyst.
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