Synergistic effects of a copper-cobalt-nitroisophthalic acid/neodymium oxide composite on the electrochemical performance of hybrid supercapacitors.

RSC advances(2024)

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摘要
Hybrid supercapacitors can produce extraordinary advances in specific power and energy to display better electrochemical performance and better cyclic stability. Amalgamating metal oxides with metal-organic frameworks endows the prepared composites with unique properties and advantageous possibilities for enhancing the electrochemical capabilities. The present study focused on the synergistic effects of the CuCo(5-NIPA)-Nd2O3 composite. Employing a half-cell configuration, we conducted a comprehensive electrochemical analysis of CuCo(5-NIPA), Nd2O3, and their composite. Owing to the best performance of the composite, the hybrid device prepared from CuCo(5-NIPA)-Nd2O3 and activated carbon demonstrated a specific capacity of 467.5 C g-1 at a scan rate of 3 mV s-1, as well as a phenomenal energy and power density of 109.68 W h kg-1 and 4507 W kg-1, respectively. Afterwards, semi-empirical techniques and models were used to investigate the capacitive and diffusive mechanisms, providing important insights into the unique properties of battery-supercapacitor hybrids. These findings highlight the enhanced performance of the CuCo(5-NIPA)-Nd2O3 composite, establishing it as a unique and intriguing candidate for applications requiring the merging of battery and supercapacitor technologies.
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