Synthesis of ¹⁰B-enriched 2,1-borazaronaphthalenes from o-aminostyrenes and ¹⁰BF₃

Weihua Qiu, Jide Zhu, Rencai Tao,Kai Yang,Qiuling Song

Organic Chemistry Frontiers（2024）

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摘要

Herein we present a practical approach for preparing 10B-enriched 2,1-borazaronaphthalenes from o-aminostyrenes and 10BF3 (the primary source of boron-10) in the presence of chlorosilane.

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Synthesis of 10B-enriched 2,1-borazaronaphthalenes from o-aminostyrenes and 10BF3

Synthesis of ¹⁰B-enriched 2,1-borazaronaphthalenes from o-aminostyrenes and ¹⁰BF₃