High-Performance All-Solid-State Lithium Metal Batteries Enabled by Ionic Covalent Organic Framework Composites
ADVANCED ENERGY MATERIALS(2024)
摘要
Ionic covalent organic frameworks (iCOFs) are crystalline materials with stable porous structures. They hold great potential for ion transport, particularly as solid-state electrolytes (SSEs) for all-solid-state lithium metal batteries (ASSLMBs). However, achieving an ionic conductivity of over 10(-3) S cm(-1) at room temperature using pure-iCOF-based SSEs, even adding additives such as lithium salts, is challenging as the voids work as strong resistances. Thus, highly conductive iCOFs typically require quasi-solid-state configurations with organic solvents or plasticizers. In this study, composites comprising iCOFs and poly(ionic liquid) (PIL) are prepared to make all-solid-state iCOFs electrolytes with an exceptional ionic conductivity up to 1.50 x 10(-3) S cm(-1) and a high Li+ transference number of > 0.80 at room temperature. Combined experimental and computational studies show that the co-coordination and competitive coordination mechanism established between the PIL, lithium bis(trifluoromethanesulfonyl)imide (LiTFSI), and iCOFs enabled rapid Li+ transport while restricting TFSI- movement. ASSLMB cells, made of composite SSEs and LiFePO4 composite cathode, demonstrate an initial discharge capacity of 141.5 mAh g(-1) at 1C and r.t., with an impressive capacity retention of 87% up to 800 cycles. Overall, this work presents a breakthrough approach for developing advanced SSEs for next-generation high-energy-density ASSLMBs.
更多查看译文
关键词
all-solid-state electrolytes,covalent organic frameworks,lithium metal batteries,poly(ionic liquid)
AI 理解论文
溯源树
样例
生成溯源树,研究论文发展脉络
Chat Paper
正在生成论文摘要