Nd-doping-induced perovskite/Ruddlesden-Popper heterointerfaces boost the ORR activity and CO2 tolerance for SrFeO3--based cathode

The development of cathode materials with high oxygen reduction reaction (ORR) activity is crucial to realize the wide application of solid oxide fuel cells. Nd-doped SrFeO3-delta (SNF) two-phase nanocomposite was fabricated by a dopant-induced in situ self-assembly process. The SNF nanocomposite comprises 63.4 wt% perovskite main phase (P-SNF) and 36.6 wt% Ruddlesden-Popper second phase (RP-SNF). The average thermal expansion coefficient (TEC) of SrFeO3-delta is reduced by 36.5 % and down to 13.9 x 10-6 K-1. At 750 degrees C, SNF demonstrates an impressive output power of 779 mW cm-2, which is twice that of the single-phase SrFeO3-delta. The superior performance stems from the heterointerface effect of the in situ self-assembled two phases. This effect increases the content of oxygen vacancies, thereby enhancing both chemical oxygen surface exchange coefficient and bulk diffusion coefficient. Moreover, the SNF composite exhibits excellent CO2 tolerance than the single-phase SrFeO3-delta. This work presents a promising avenue for exploring multifunctional materials through interface engineering, offering new possibilities for future energy conversion devices.