Modular Assembly of 2-Aminoaniline Derivatives by Merging Hydroxylamine-Passerini and Hetero-Cope Rearrangement

Ning Yu, Jing-Fang Lv, Shi-Mei He,Kui-Cheng He,Wei-Hao Zheng,Yu-Qiang Zhou,Kun Jiang,Xi-Chun Pan,Ye Wei

ORGANIC LETTERS（2024）

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摘要

A metal-free three-component protocol that combines a hydroxylamine-Passerini reaction and hetero-Cope rearrangement was realized, which enables the modular assembly of a wide range of structurally new and interesting 2-aminoanilines bearing an alpha-hydroxyamide substructure.

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