Fluid metasomatism of subducted continental crust: Insights from Si isotope compositions of metasomatic rocks from the Western and Eastern Alps

Serpentinite-derived fluids play a crucial role in mass exchange between the Earth's crust and mantle. However, there is currently a limited understanding of how serpentinite-derived fluids influence the Si isotope composition of mantle and subducted crustal materials. Whiteschists in the Dora-Maira Massif of the Western Alps and leucophyllites in Austria of the Eastern Alps were formed through serpentinite-derived fluid metasomatism of metagranite protoliths. Thus, they can provide valuable insights into the geochemical diversity of such rocks resulting from fluid-rock interactions. A special focus is on Si isotope compositions, which were analyzed in whiteschists, leucophyllites, and their corresponding country rocks. The aim of this paper is to investigate the impact of serpentinite-derived metasomatic fluids on the Si isotope compositions of subducted continental crust. With the exception of one whiteschist sample, which contains high amounts of pyrope, and one pyrope megablast, all other whiteschists and leucophyllites exhibit Si isotope compositions similar to those of their country rocks. This observation suggests that the Si isotopes of whiteschists and leucophyllites were inherited from their respective country rocks; fluid metasomatism did not significantly modify the Si isotope compositions of whiteschists and leucophyllites. Because pyrope has much lower delta 30Si values than quartz and phengite as further major mineral constituents of the studied whiteschists, the samples with high pyrope contents reveal lighter Si isotopes than those containing lower amounts of pyrope. Interestingly, the metagranites and the majority of whiteschists and leucophyllites exhibit Si isotope compositions below the igneous array, implying that their protoliths are S-type granites. These granites commonly contain sedimentary components derived from their sources. Our results document that Si behaves immobile during serpentinite-derived fluid metasomatism of the subducted continental crust. Combined with previous results, we were able to show that slab derived fluids, including serpentinite-derived fluids, produce only a minimal influence on the Si isotope composition of the overlying mantle wedge and its derived magmas. Thus, the Si isotope compositions of rocks, even if highly affected by metasomatizing fluids, can be used as significant fingerprints that refer to their unaltered precursors.