Simultaneous catalytic oxidation of toluene and CO over Cu-V/Al-Ce catalysts: Physicochemical properties-activity relationship and simultaneous oxidation mechanism

Cu-V/Al-Ce with varying ratios of Al2O3/CeO2 were prepared to study the simultaneous catalytic oxidation of toluene and CO. Experimental results show that Cu-V/20Al-80Ce exhibits optimal simultaneous oxidation activity and good durability. This superior performance is related to Cu-Ce, V-Ce, and Al-Ce interactions, which facilitates the exposure of active centers, the creation of OVs, and efficient electron transfer. The mutual influence between toluene and CO during the simultaneous oxidation is then demonstrated. Toluene hinders CO oxidation through the competitive adsorption and the consumption of reactive oxygen species. CO enhances toluene oxidation, which is comprehensively explained by affecting the competition between the desorption and oxidation of benzaldehyde. Despite the mutual influence between toluene and CO, the pathways of CO and toluene oxidation are mutually independent. Toluene oxidation proceeds sequentially from toluene to benzyl alcohol, benzaldehyde, benzoate, and finally to CO2. Before being completely oxidized to CO2, CO is initially converted to carboxylic acid, hydrogen carbonate, free carbonate ion, bidentate formate, and monodentate carbonate.