Catalytic condensation of α-pinene with formaldehyde

A.Yu. Sidorenko,Yu.M. Kurban,I.V. Il'ina, N.S. Li-Zhulanov, O.S. Patrusheva, V.V. Goltsova,M.P. Bei, A. Aho, J. Wärnå, I. Heinmaa, T.F. Kouznetsova, K.P. Volcho, N.F. Salakhutdinov,D.Yu. Murzin, V.E. Agabekov

Journal of Catalysis（2024）

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摘要

•Condensation of (–)-α-pinene with formaldehyde into 8-acetoxy-6-hydroxymethyllimonene.•Selectivity of 24 % with traditional Lewis and Brønsted acids (ZnCl2, FeCl3, H3PO4).•Comparable selectivity for strongly acidic H-Beta-25 zeolite and phosphoric acid.•Reaction mechanism elucidated using kinetic and quantum chemical approaches.•Successful scaling up 8-acetoxy-6-hydroxymethyllimonene synthesis.

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关键词

α-Pinene,Formaldehyde,Prins condensation,8-Acetoxy-6-hydroxymethyllimonene,Chiral platform,Phosphoric acid,Halloysite nanotubes

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