Crystallization Kinetics of Hybrid Perovskite Solar Cells

Zhiwei Wu, Shuyang Sang, Junjian Zheng, Qin Gao,Bin Huang,Feng Li,Kuan Sun,Shanshan Chen

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION(2024)

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摘要
Metal halide perovskites (MHPs) are considered ideal photovoltaic materials due to their variable crystal material composition and excellent photoelectric properties. However, this variability in composition leads to complex crystallization processes in the manufacturing of Metal halide perovskite (MHP) thin films, resulting in reduced crystallinity and subsequent performance loss in the final device. Thus, understanding and controlling the crystallization dynamics of perovskite materials are essential for improving the stability and performance of PSCs (Perovskite Solar Cells). To investigate the impact of crystallization characteristics on the properties of MHP films and identify corresponding modulation strategies, we primarily discuss the relevant aspects of MHP crystallization kinetics, systematically summarize theoretical methods, and outline modulation techniques for MHP crystallization, including solution engineering, additive engineering, and component engineering, which helps highlight the prospects and current challenges in perovskite crystallization kinetics Metal halide perovskites (MHPs) are outstanding photovoltaic materials. Nonetheless, despite significant progress, perovskite solar cells (PSCs) still face challenges. It is crucial to adjust the crystallization process during solution crystallization and film formation to overcome this challenge. We primarily discuss the relevant aspects of MHP crystallization kinetics, systematically summarize theoretical methods, and outline modulation techniques for MHP crystallization, including solution engineering, additive engineering, and component engineering. image
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关键词
perovskite solar cell,crystallization kinetics,solvent engineering,additive engineering,interface engineering
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