Highly selective photothermal conversion of CO₂ to ethylene using hierarchical boxwood ball-like Weyl semimetal WTe₂ catalysts

It is of significance to convert CO2 into value-added carbon compounds under solar light. Here, we report a WTe2 photothermal catalyst for the highly selective conversion of CO2 into a commercially valuable chemical, ethylene (C2H4), by using the dual sites of W and Te under light illumination. It is found that (1) WTe2 offers favorable formation of a *CHO intermediate at the W site, a lower energy barrier for the transfer of the *CHO intermediate from the W to the Te site, and a suitable W-Te distance for the C-C coupling to produce C2H4; (2) the photocatalysis and thermocatalysis synergistically cooperate with each other on WTe2, significantly facilitating the CO2 conversion. As a result, by designing a WTe2 nanostructure with an enhanced photothermal effect, the reaction temperature can reach 185 degrees C under a 300 W Xe lamp, enabling a C2H4 production rate of 115.51 mu mol g(-1) with a selectivity of C2H4 up to 88%, which exceeds all reported values of solar-driven C2H4 production.