Dissolved greenhouse gas (CO2, CH4, and N2O) emissions from highland lakes of the Andes cordillera in Northern Ecuador

We report, in 15 Ecuadorian mountainous lakes, dissolved concentrations of CO2, CH4, and N2O and a suite of ancillary biogeochemical variables (dissolved inorganic nutrients, oxygen, major cations, dissolved and particulate organic carbon, and the stable isotope composition of dissolved inorganic carbon and water). The sampled lakes were located in the páramos of Salve Facha and Antisana y Mojanda (northern region of Ecuadorian Andes), along an elevational gradient from 2213 to 4361 m above sea level, as well as a gradient of lake surface area (0.003–6.1 km2) and depth (1–74 m). Most lakes were characterized by lower values of the partial pressure of CO2 (pCO2) (644–2152 ppm) than usually attributed to tropical lakes ( 1900 ppm). Three lakes influenced by volcanic inputs were characterized by the highest pCO2 values (3269–10,069 ppm), while two lakes bordered by large cities were characterized by the lowest pCO2 values (208–254 ppm). Dissolved CH4 concentrations ranged between 170 and 24,908 nmol/L and were negatively correlated to lake area and depth. N2O saturation levels ranged between 64