Unveiling the mechanism of electrocatalytic oxidation of glycerol by in-situ electrochemical spectroscopy
CHEMICAL ENGINEERING JOURNAL(2024)
摘要
The electrocatalytic glycerol oxidation reaction (GOR) is an efficient way to reduce the overpotential of the anodic reaction of electrocatalytic water splitting with abundant high-value byproducts. However, it has always been difficult to reveal a clear reaction path and real active site during the electrocatalytic glycerol oxidation reaction (GOR) process. In this work, NiOOH/Ni3S2/NF, a model catalyst was synthesized by the two-step method, and the reaction path of the electrocatalytic oxidation of glycerol on NiOOH/Ni3S2/NF was clearly unveiled by the in situ infrared and Raman analysis. In addition, the TEM after GOR and in-situ Raman intuitively demonstrated that the NiOOH was the real active site during the GOR process. Consequently, the synthesized NiOOH/Ni3S2/NF catalyst achieved a current density of 10 mA cm-2 at 1.227 V vs. RHE and obtained a high formic acid Faraday efficiency of 97.7 % at a low potential of 1.4 V vs. RHE. This work demonstrates an effective method for unveiling the GOR mechanism and the other relevant electrocatalytic reaction processes.
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关键词
Heterojunction,Electrocatalytic glycerol oxidation reaction,In -situ electrochemical spectroscopy
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