Reconstructing the timing and conditions of fragmentation from water speciation in ash during a deep submarine eruption: 2012 eruption of Havre, Kermadec Arc

The lack of visual observations and difficulty recreating ambient conditions in the laboratory mean deep subaqueous volcanic eruptions (>500 m water depth) remain enigmatic. However, the pressure and temperature dependency of water speciation and solubility in volcanic melts and glasses, and water's high diffusion rate, offers a potential window into the processes and conditions during deep subaqueous volcanism. The 2012 submarine eruption of Havre Volcano is the ideal laboratory in which to use water species distributions to understand submarine eruption processes. Post-eruption AUV mapping, and ROV observation and sampling generated an unprecedented amount of contextual information for a deep submarine eruption including on the magma ascent conditions, eruption sequence, and magma fragmentation. Here we present high spatial resolution synchrotron-FTIR measurements of water speciation in glassy ash (125-500 mu m) from several subunits (1, 2 and 3) of a widespread ash with lapilli deposit produced in the 2012 eruption. Measurements record OH depletion profiles around vesicles, along with H2Omol enrichment profiles. In several thick vesicle walls far-field regions unaffected by processes at the bubble margins have also been identified. By focusing on OH concentrations, which is effectively non-diffusing below the glass transition, we can remove the effects of secondary rehydration and calculate the pressure and water depth at which ash grain quenched. Far-field regions record quench depths within the 650-900 m water depth range for pre- and post- eruption vent depth, suggesting ash grains equilibrated at vent depth. OH depletion profiles produce quench pressures on vesicle margins typically corresponding to 200-400 m water depth shallower, suggesting a 2-4 MPa decompression before ash quench. Diffusion modelling suggests that at eruption temperature the observed OH depletion profiles formed through exsolution in <2 s. The difference in quench pressure within the ash is not reflective of a difference in the depth of quenching. Rather it is reflective of the rapidity of the quench process relative to the diffusion rate. The results imply transient low-pressure conditions formed during ash generation in the 2012 Havre eruption. We discuss several physical processes in the context of submarine volcanism that may explain the formation of transient low-pressure regions. The results have implications for how we understand submarine eruption processes and highlight the potential of high resolution FTIR for studying submarine volcanism.