Provenance shifts in bauxitic clay from Zibo, North China Craton links tectonics and climate to environmental perturbation

In the eastern North China Craton, the Zibo bauxitic clay deposits are situated between Permian sandstones. These deposits exhibit distinct characteristics in two horizons. The lower horizon consists of disordered kaolinite with anhedral- subhedral, rounded morphologies that indicate a detrital origin. The upper horizon, however, contains ordered kaolinite. Detrital zircon grains in the lower horizon indicate a unimodal age spectrum with a mean age of ca. 290 Ma and epsilon Hf(t) values ranging from -20.8 to -6.0. These findings suggest a continental volcanic arc source on the northern margin of the North China Craton. In contrast, detrital zircon grains in the upper section exhibit a multi -modal detrital age spectrum with significant age peaks at 2500 Ma, 1850 Ma, and 310 Ma that originates from the local basement. The zircon dating establishes a maximum depositional age of ca. 280 +/- 3 Ma, which indicates denudation of the source area in the northern North China Craton during the Artinskian stage. The relative abundance of detrital kaolinite indicates a warm and humid climate during the late Artinskian (ca. 283 Ma) to Early Kungurian (ca. 280 Ma), while cold and dry conditions prevailed during the mid- late Kungurian (ca. 277 Ma). The northern North China Craton, which supplied source material to the lower section of Zibo bauxitic clay, experienced rapid uplift and exhumation and underwent intense weathering under high humidity and warm temperatures during the late Artinskian to Early Kungurian. However, the source area shifted from the north to a more central region as the climate transitioned to cold and dry conditions in the mid- late Kungurian. Considering that detrital clay formation is indicative of specific climatic conditions, the Permian bauxitic clay deposits in Zibo provide a valuable record of environmental changes during the late Paleozoic ice age (LPIA; ca. 360- 260 Ma).