Helix-forming aliphatic homo-δ-peptide foldamers based on the conformational restriction effects of cyclopropane

Michio Nagata,Mizuki Watanabe,Ryohei Doi, Matsuo Uemura,Nanase Ochiai,Wataru Ichinose,Koichi Fujiwara,Yoshihiro Sato,Tomoshi Kameda,Koh Takeuchi,Satoshi Shuto

Organic and Biomolecular Chemistry（2023）

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摘要

This work reports the first aliphatic homo-δ-peptide helical foldamer consisting of a conformationally restricted δ-amino acid, where the structural characteristics of cyclopropane tightly control the backbone torsion angles.

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关键词

cyclopropane,conformational restriction effects,helix-forming

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