EuCd2As2 : A Magnetic Semiconductor

David Santos-Cottin, I. Mohelský, J. Wyzula,F. Le Mardelé, I. Kapon, S. Nasrallah,N. Barišić, I. Živković,Jian-Rui Soh, Fengqi Guo, K. Rigaux, M. Puppin,J. Hugo Dil, B. Gudac,Zoran Rukelj,Mario Novak, A. B. Kuzmenko, C. C. Homes, T. Dietl, М. Орлита,Ana Akrap

Physical Review Letters(2023)

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摘要
${\mathrm{EuCd}}_{2}{\mathrm{As}}_{2}$ is now widely accepted as a topological semimetal in which a Weyl phase is induced by an external magnetic field. We challenge this view through firm experimental evidence using a combination of electronic transport, optical spectroscopy, and excited-state photoemission spectroscopy. We show that the ${\mathrm{EuCd}}_{2}{\mathrm{As}}_{2}$ is in fact a semiconductor with a gap of 0.77 eV. We show that the externally applied magnetic field has a profound impact on the electronic band structure of this system. This is manifested by a huge decrease of the observed band gap, as large as 125 meV at 2 T, and, consequently, by a giant redshift of the interband absorption edge. However, the semiconductor nature of the material remains preserved. ${\mathrm{EuCd}}_{2}{\mathrm{As}}_{2}$ is therefore a magnetic semiconductor rather than a Dirac or Weyl semimetal, as suggested by ab initio computations carried out within the local spin-density approximation.
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magnetic semiconductor
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