B(C₆F₅)₃‐Catalyzed E‐Selective Isomerization of Alkenes

Betty A Kustiana,Salma A Elsherbeni,Thomas G. Linford-Wood,Rebecca L. Melen,Matthew N. Grayson,Louis C. Morrill

Chemistry - A European Journal（2022）

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摘要

Herein, we report the B(C6 F5 )3 -catalyzed E-selective isomerization of alkenes. The transition-metal-free method is applicable across a diverse array of readily accessible substrates, giving access to a broad range of synthetically useful products containing versatile stereodefined internal alkenes. The reaction mechanism was investigated by using synthetic and computational methods.

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bc6f53‐catalyzed

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B(C6F5)3‐Catalyzed E‐Selective Isomerization of Alkenes

B(C₆F₅)₃‐Catalyzed E‐Selective Isomerization of Alkenes