Emission characteristics of VOCs emitted from household stove combustion in the north of China

The emissions of volatile organic compounds (VOCs) arising from household stove combustion of different fuels common in North China were quantified. Using a dilution tunnel sampling system and gas chromatography-mass spectrometry analysis, 107 different C2-C12 VOCs were identified in flue gases of four household solid fuels (coal briquette, honeycomb briquette, wood, and cornstalk), whose emission factors were 670 +/- 550, 1322 +/- 686, 1200 +/- 1923, 8670 +/- 8380 mg kg-1, respectively. Alkenes and alkynes contributed the most to the VOC emitted from the combustion of honeycomb briquettes (50.1%), wood (46.3%), and cornstalks (56.9%). N-Alkanes were the dominant VOC (43.9%) from coal briquette combustion. Ethane and ethene were the most abundant individual species found in the flue gas of coal briquettes, wood, and cornstalks, accounting for 60.4%, 59.8%, and 67.9% of the emissions, respectively. The VOC emitted from coal briquettes, honeycomb briquettes, wood, and cornstalks exhibited significantly different chemical reactivities. The OH reactivity of the VOCs from cornstalk combustion was 9-270 times greater than that of the other fuels. The differences in the atmospheric reactivity of emissions would suggest that cornstalk combustion should be prioritised in any strategy to reduce ozone pollution.