Innovative process integrating high temperature heat pump and direct air capture

Direct air capture (DAC) technology plays a crucial role in mitigating the effects of global warming by capturing carbon dioxide (CO2) directly from the atmosphere. A significant technical challenge for DAC is its high thermal energy consumption, which results in an unacceptable overall cost (600 $ t-1 CO2 ). The combination of a hightemperature heat pump (HTHP) and DAC system offers a substantial reduction in thermal energy consumption, decreased reliance on renewable energy sources, and enhanced DAC system flexibility. This study presents three distinct thermal integration strategies that combine an HTHP with solid adsorbent-based DAC and verifies their effectiveness in reducing energy consumption and CO2 emissions compared to a traditional DAC system. Among them, the deeply integrated DAC-HTHP system (I-DAC) exploits low-grade adsorption heat and waste heat, providing direct heating and cooling energy to the DAC system via refrigerant condensation and evaporation processes. Simulation results indicate that the I-DAC system achieves an extremely low operating energy consumption of 2.77 GJ t-1 CO2, representing a 69.5% reduction than traditional DAC under the same conditions. Consequently, the I-DAC offers a cost-effective (32.0-46.2 $ t-1CO2) negative emission solution. We also demonstrate that the I-DAC is promising for wide application in cities to recycle waste heat and remove CO2 from the air. The comprehensive implementation of the I-DAC in 105 cities could yield a net annual productivity of 980 MtCO2.