Synthesis of Tetrahydronaphthoazetidinones, 2,5‐Dioxo‐1,4‐methanobenzoazepines and 3‐Hydroxypyrrolidinones Through Copper‐Assisted Post‐Ugi Reactions

Javier Gómez‐Ayuso, Mario Lezcano,Israel Carreira‐Barral,Beatriz González‐Saiz,Roberto Quesada,María García‐Valverde

ADVANCED SYNTHESIS & CATALYSIS（2023）

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摘要

Copper-assisted post-Ugi reactions enable access to different heterocyclic systems, tetrahydronaphthoazetidinone, 2,5-dioxo-1,4-methanobenzoazepine and 3-hydroxypyrrolidinone derivatives. The described process affords complex scaffolds from readily available acyclic precursors using simple protocols. image

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关键词

Multicomponent reactions, radical reactions, copper, lactams, post-Ugi reactions

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