Self-formed MnCO3/FeS2@SiO2 in modified electrolytic manganese residues as an enhanced peroxymonosulfate activator for ammonium dibutyl dithiophosphate removal

Hairong Shen, Mengqi Luo,Jieyi Wang,Mengke Li,Zhiguo He,Hui Zhong,Wei Sun,Mingqiang Ye,Yetao Tang

CHEMICAL ENGINEERING JOURNAL（2023）

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摘要

•Alkali modification of EMR could prepare MnCO3/FeS2@SiO2 composites.•O2•− and 1O2 played the crucial role in decomposing the ADD molecule.•Fe, Mn and reducing S species have synergistic effects.

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关键词

Ammonium dibutyl dithiophosphate,Electrolytic manganese residue,Manganese carbonate,Peroxymonosulfate,Pyrite

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